Artículo
Effect of PAA-coated magnetic nanoparticles on the performance of PVA-based hydrogels developed to be used as environmental remediation devices
Sanchez, Laura Mabel
; Actis, Daniel Guillermo
; Gonzalez, Jimena Soledad
; Mendoza Zélis, Pedro
; Alvarez, Vera Alejandra
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Fecha de publicación:
03/2019
Editorial:
Springer
Revista:
Journal of Nanoparticle Research
ISSN:
1388-0764
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
In the present work, the effect of the incorporation of polyacrylic acid (PAA)–coated magnetic nanoparticles (MNPs) on the performance of polyvinyl alcohol (PVA)–based hydrogels for water remediation was studied. Ferrogels from PVA and PAA-coated MNPs were prepared through the ecocompatible freezing–thawing physical cross-linking method, and then they were completely characterized. Two different lab-made PAA-coated iron oxide MNPs, characterized in a previous work, were prepared by coprecipitation method from two different low PAA molecular weights, Mw 1800 g/mol and 5000 g/mol. The effect of MNP content and the PAA Mw on ferrogel final properties was determined. In addition, adsorption of methylene blue (MB) and cadmium (Cd+2) was carried out to analyze the possible application of the developed materials as environmental remediation devices. The capture of a ferrogel by an external field occurs due to the force that the field gradient exerts on single magnetic particles, which is then transferred onto the polymer matrix. This force was measured as a function of the distance to a permanent magnet, and the condition to magnetically recover the sample was established. The results obtained demonstrated that the ferrogels presented in this work are able to adsorb heavy metals and then be magnetically separated.
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Articulos(IFLP)
Articulos de INST.DE FISICA LA PLATA
Articulos de INST.DE FISICA LA PLATA
Articulos(INTEMA)
Articulos de INST.DE INV.EN CIENCIA Y TECNOL.MATERIALES (I)
Articulos de INST.DE INV.EN CIENCIA Y TECNOL.MATERIALES (I)
Citación
Sanchez, Laura Mabel; Actis, Daniel Guillermo; Gonzalez, Jimena Soledad; Mendoza Zélis, Pedro; Alvarez, Vera Alejandra; Effect of PAA-coated magnetic nanoparticles on the performance of PVA-based hydrogels developed to be used as environmental remediation devices; Springer; Journal of Nanoparticle Research; 21; 64; 3-2019; 1-16
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