Artículo

Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling: The role of water and copper(I) salts

Traficante, Carla InésIcon ; Mata, Ernesto GabinoIcon ; Delpiccolo, Carina Maria LujanIcon
Fecha de publicación: 03/2015
Editorial: Royal Society of Chemistry
Revista: RSC Advances
ISSN: 2046-2069
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

A very high-yielding Pd-catalyzed cross-coupling between aryl halides and aryl(trialkoxy)silanes is achieved in the presence of Cu(i) and a measured amount of water. This novel methodology is useful for the generation of a wide range of biaryls, particularly non-para substituted derivatives, which are usually less reported.
Palabras clave: Cross-coupling reactions , Biaryl derivatives , Hiyama coupling
 
Archivos asociados
Thumbnail
 
Tamaño: 1.987Mb
Formato: PDF
.
Licencia
info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial 2.5 Unported (CC BY-NC 2.5)
Identificadores
URI: http://hdl.handle.net/11336/127128
DOI: http://dx.doi.org/10.1039/c5ra03732h
URL: https://pubs.rsc.org/en/content/articlelanding/2015/RA/C5RA03732H#!divAbstract
Colecciones
Articulos(IQUIR)
Articulos de INST.DE QUIMICA ROSARIO
Citación
Traficante, Carla Inés; Mata, Ernesto Gabino; Delpiccolo, Carina Maria Lujan; Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling: The role of water and copper(I) salts; Royal Society of Chemistry; RSC Advances; 5; 34; 3-2015; 26796-26800
Compartir
Altmétricas