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dc.contributor.author
Puszkiel, Julián Atilio
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dc.contributor.author
Bellosta von Colbe, José M.
dc.contributor.author
Jepsen, Julian
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dc.contributor.author
Mitrokhin, Sergey V.
dc.contributor.author
Movlaev, Elshad
dc.contributor.author
Verbetsky, Victor
dc.contributor.author
Klassen, Thomas
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dc.date.available
2021-02-25T19:55:12Z
dc.date.issued
2020-06
dc.identifier.citation
Puszkiel, Julián Atilio; Bellosta von Colbe, José M.; Jepsen, Julian; Mitrokhin, Sergey V.; Movlaev, Elshad; et al.; Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept; Multidisciplinary Digital Publishing Institute; Energies; 13; 11; 6-2020; 1-26
dc.identifier.uri
http://hdl.handle.net/11336/126699
dc.description.abstract
The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB2 C14-Laves alloy composed of (Ti0.9Zr0.1)1.25Cr0.85Mn1.1Mo0.05. This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 ◦C and from 15 to 500 bar: ∆Habs. = 22 ± 1 kJ/mol H2, ∆Sabs. = 107 ± 2 J/K mol H2, and ∆Hdes. = 24 ± 1 kJ/mol H2, ∆Sdes. = 110 ± 3 J/K mol H2. The addition of 10 wt.% of expanded natural graphite (ENG) allows the improvement of the heat transfer properties, showing a reversible capacity of about 1.5 wt.%, cycling stability and hydrogenation/dehydrogenation times between 25 to 70 s. The feasibility for the utilization of the designed material in a high-pressure tank is also evaluated, considering practical design parameters.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Multidisciplinary Digital Publishing Institute
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by/2.5/ar/
dc.subject
AB2 ALLOY
dc.subject
COMPRESSED HYDROGEN
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HYBRID
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HYDROGEN STORAGE
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KINETICS
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METAL HYDRIDE
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THERMODYNAMICS
dc.subject.classification
Ingeniería de los Materiales
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dc.subject.classification
Ingeniería de los Materiales
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-02-24T12:02:58Z
dc.identifier.eissn
1996-1073
dc.journal.volume
13
dc.journal.number
11
dc.journal.pagination
1-26
dc.journal.pais
Suiza
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dc.description.fil
Fil: Puszkiel, Julián Atilio. Helmholtz-zentrum Geesthacht; Alemania. Instituto de Investigaciones Energéticas de Cataluña; España. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada CAB. Departamento Fisicoquímica de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
dc.description.fil
Fil: Bellosta von Colbe, José M.. Helmholtz-zentrum Geesthacht; Alemania
dc.description.fil
Fil: Jepsen, Julian. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; Alemania
dc.description.fil
Fil: Mitrokhin, Sergey V.. Lomonosov Moscow State University; Rusia
dc.description.fil
Fil: Movlaev, Elshad. Lomonosov Moscow State University; Rusia
dc.description.fil
Fil: Verbetsky, Victor. Lomonosov Moscow State University; Rusia
dc.description.fil
Fil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; Alemania
dc.journal.title
Energies
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/13/11/2751
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.3390/en13112751
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