Artículo

Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes

Parajón Costa, Beatriz SusanaIcon ; Baran, Enrique JoséIcon ; Romero, Julio; Saez Puche, Regino; Arrambide, Gabriel; Gambino, Dinorah
Fecha de publicación: 01/2011
Editorial: Taylor & Francis Ltd
Revista: Journal of Coordination Chemistry
ISSN: 0095-8972
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Oxovanadium(IV) and oxovanadium(V) complexes of tropolone (Htrp, 2-hydroxi-2,4,6-cycloheptatrien-1-one), of stoichiometry VO(trp)2 and VO(trp)2Cl, were characterized by electronic, infrared and Raman spectroscopy. Their electrochemical behavior was investigated by cyclic voltamperommetry in dimethylsulfoxide solutions. The magnetic susceptibility of VO(trp)2 was investigated in the temperature range between 2 and 300 K. The vibrational spectra of the related Co(trp)2, Cu(trp)2 and Zn(trp)2 complexes were also analyzed for comparative purposes. 
Palabras clave: Tropolone , Oxovanadium complexes , Electronic spectra , IR and Raman spectra , Cyclic voltamperommetry , Magnetic susceptibility
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/124954
DOI: http://dx.doi.org/10.1080/00958972.2010.531131
URL: https://www.tandfonline.com/doi/full/10.1080/00958972.2010.531131
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Articulos(CEQUINOR)
Articulos de CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Citación
Parajón Costa, Beatriz Susana; Baran, Enrique José; Romero, Julio; Saez Puche, Regino; Arrambide, Gabriel; et al.; Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes; Taylor & Francis Ltd; Journal of Coordination Chemistry; 64; 1; 1-2011; 57-70
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