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dc.contributor.author
Baran, Enrique José
dc.contributor.author
Parajón Costa, Beatriz S.
dc.contributor.author
Mercader, Roberto Carlos
dc.date.available
2021-02-04T16:54:13Z
dc.date.issued
2019-07
dc.identifier.citation
Baran, Enrique José; Parajón Costa, Beatriz S.; Mercader, Roberto Carlos; Spectroscopic characterization of NH4FeP2O7; Elsevier Science; Journal of Molecular Structure; 1188; 7-2019; 234-237
dc.identifier.issn
0022-2860
dc.identifier.uri
http://hdl.handle.net/11336/124799
dc.description.abstract
The mixed cation diphosphate of composition NH4FeP2O7 has been prepared by heating of adequate mixtures of NH4(H2 PO4) and Fe(NO3)3 ⋅9H2O in concentrated phosphoric acid, and characterized by X-ray powder diffractometry. Its infrared and Raman spectra were recorded and briefly analyzed on the basis of the structural peculiarities of the P2O74− anion and the NH4+ cation, which is demonstrated, do not rotate freely in the lattice. Its 57Fe-Mössbauer spectrum shows that the typical high-spin FeIII O6 octahedra present in the compound exhibit almost no distortion.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
AMMONIUM IRON DIPHOSPHATE
dc.subject.classification
Química Inorgánica y Nuclear
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Spectroscopic characterization of NH4FeP2O7
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2020-05-04T20:42:19Z
dc.journal.volume
1188
dc.journal.pagination
234-237
dc.journal.pais
Países Bajos
dc.description.fil
Fil: Baran, Enrique José. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina
dc.description.fil
Fil: Parajón Costa, Beatriz S.. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina
dc.description.fil
Fil: Mercader, Roberto Carlos. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina
dc.journal.title
Journal of Molecular Structure
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://doi.org/10.1016/j.molstruc.2019.03.099
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0022286019303825?via%3Dihub
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