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dc.contributor.author
Monasterio, Fernanda Elena  
dc.contributor.author
Pita, Victor Rodriguez  
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Dias, Marcos Lopes  
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Erdmann, Eleonora  
dc.contributor.author
Destefanis, Hugo Alberto  
dc.date.available
2020-12-15T19:53:26Z  
dc.date.issued
2011-01  
dc.identifier.citation
Monasterio, Fernanda Elena; Pita, Victor Rodriguez; Dias, Marcos Lopes; Erdmann, Eleonora; Destefanis, Hugo Alberto; Thermal and rheological properties of polyethylene composites based on poly(diphenylsiloxanes)/organoclay hybrids obtained from two different silanes; Wiley; Macromolecular Symposia; 299-300; 1; 1-2011; 81-91  
dc.identifier.issn
1022-1360  
dc.identifier.uri
http://hdl.handle.net/11336/120516  
dc.description.abstract
Poly(diphenylsiloxanes) (PDPhS) were synthesized in presence of organophilic clay in order to modify its nanostructure. Two silane monomers were used: dimethoxydiphenylsilane and dichlorodiphenylsilane. The following characterizations were performed for all clays: XRD, FTIR, TG/DTG and SEM. These siloxane‐modified clays were more hydrophobic and had enhanced thermal stability. Solvent extraction was carried out in the siloxane‐modified clays and the PDPhS soluble fraction analyzed according the molecular weight via GPC. The presence of free and grafted oligomers on clay surface was identified. The modified clays were added to high density polyethylene (HDPE) by melt processing to obtain HDPE/hybrid clay composites which exhibited marked differences on macroscopic properties when compared with neat HDPE.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Wiley  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
CLAY  
dc.subject
HDPE  
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INORGANIC/ORGANIC HYBRIDS  
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OLIGOMERS  
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POLY(DIPHENYLSILOXANE)  
dc.subject.classification
Compuestos  
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Ingeniería de los Materiales  
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INGENIERÍAS Y TECNOLOGÍAS  
dc.title
Thermal and rheological properties of polyethylene composites based on poly(diphenylsiloxanes)/organoclay hybrids obtained from two different silanes  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2020-12-10T13:30:38Z  
dc.journal.volume
299-300  
dc.journal.number
1  
dc.journal.pagination
81-91  
dc.journal.pais
Alemania  
dc.description.fil
Fil: Monasterio, Fernanda Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina  
dc.description.fil
Fil: Pita, Victor Rodriguez. Universidade Federal do Rio de Janeiro; Brasil  
dc.description.fil
Fil: Dias, Marcos Lopes. Universidade Federal do Rio de Janeiro; Brasil  
dc.description.fil
Fil: Erdmann, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina  
dc.description.fil
Fil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina  
dc.journal.title
Macromolecular Symposia  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/masy.200900119/abstract  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/masy.200900119  

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