Artículo
Hydrogen purification for fuel cells through CO preferential oxidation using PtCu/Al2O3 structured catalysts
Gómez, Leticia Ester
; Sollier, Brenda Maria del Valle
; Lacoste, Albano Mauricio
; Miro, Eduardo Ernesto
; Boix, Alicia Viviana
Fecha de publicación:
10/2019
Editorial:
Elsevier Ltd
Revista:
Journal of Environmental Chemical Engineering
ISSN:
2213-3437
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Cordierite monoliths and alumina foams substrates were washcoated with PtCu/Al2O3 powder with a lowloading of Pt (0.2 and 0.5 wt. %) and 4 and 8 wt. % of Cu in order to be used for the CO Preferential Oxidation(COPrOx) reaction. These catalysts exhibited a high performance in CO oxidation at temperatures between110?130 °C. The presence of platinum caused a synergistic effect on the Cu/Al2O3 catalyst, which greatly enhancedthe CO conversion. The most active catalyst reached 100% CO conversion at 110 °C, and proved hightolerance to CO2 and H2O in the feed. A good adherence between the catalytic film and the ceramic monolithicwalls was reached after preparation by the washcoating method and calcination at 300 °C. The macropores of themonolithic wall were covered by aggregates of 2?5 μm of PtCu/Al2O3 that filled the substrate cavities. Thehigher CO conversions obtained at low temperatures were probably due to the simultaneous formation of smallPt particles in close contact with copper species. In addition, XPS data showed metallic Pt0 and Cu0 particles onthe catalytic surface of the foam and monoliths. The bimetallic monoliths with low Pt loading, very active for theCOPrOx at low temperature in the presence of CO2 and H2O, are promising catalysts for practical applications.
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Articulos(INCAPE)
Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Citación
Gómez, Leticia Ester; Sollier, Brenda Maria del Valle; Lacoste, Albano Mauricio; Miro, Eduardo Ernesto; Boix, Alicia Viviana; Hydrogen purification for fuel cells through CO preferential oxidation using PtCu/Al2O3 structured catalysts; Elsevier Ltd; Journal of Environmental Chemical Engineering; 7; 5; 10-2019; 1-10
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