Artículo

Electrosynthesis of N -Methylisatin

Martinez Suarez, Jaime FernandoIcon ; Caram, José AlbertoIcon ; Echeverría, Gustavo AlbertoIcon ; Piro, Oscar EnriqueIcon ; Gennaro, Ana MariaIcon ; Mirifico, Maria VirginiaIcon
Fecha de publicación: 05/2019
Editorial: American Chemical Society
Revista: Journal of Organic Chemistry
ISSN: 0022-3263
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Isatin in a solution of dry N,N-dimethylformamide/NaClO4 is electroreduced in the presence of CH3I. N-methylisatin (NMI) is obtained in quantitative molar yield and high current efficiency by controlled potential electrolysis (CPE). NMI and N-methylisatoic anhydride are the reaction products when CPE is performed in the absence of CH3I, but adding it once the CPE was completed. The water effect on the identity and yield of the reaction product(s) is investigated. Reaction pathways are proposed.
Palabras clave: CONTROLLED POTENTIAL ELECTROLYSIS , CYCLIC VOLTAMMETRY , ESR , X-RAY DIFFRACTION , ELECTRODE PROCESS MECHANISM , HETEROCYCLES , RADICAL ANION STABILITY
 
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/118719
URL: http://pubs.acs.org/doi/10.1021/acs.joc.9b00690
DOI: https://doi.org/10.1021/acs.joc.9b00690
Colecciones
Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Martinez Suarez, Jaime Fernando; Caram, José Alberto; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Gennaro, Ana Maria; et al.; Electrosynthesis of N -Methylisatin; American Chemical Society; Journal of Organic Chemistry; 84; 11; 5-2019; 6879-6885
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