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dc.contributor.author
Vaillard, Santiago Eduardo
dc.contributor.author
Studer, Armido
dc.contributor.other
Studer, Armido
dc.contributor.other
Chatgilialoglu, Chryssostomos
dc.date.available
2020-09-21T20:41:49Z
dc.date.issued
2012
dc.identifier.citation
Vaillard, Santiago Eduardo; Studer, Armido; Radical Arylations; John Wiley & Sons Ltd; 2; 2012; 1059-1094
dc.identifier.isbn
978-0-470-97125-3
dc.identifier.uri
http://hdl.handle.net/11336/114475
dc.description.abstract
This chapter reports on radical arylations also highlighting the very important early achievements on this chemistry. To be named at this place are the Meerwein arylation and the Pschorr reaction. Intramolecular homolytic aromatic substitutions with aryl radicals and various arene radical acceptors for formation of biaryls are discussed. Along with reactive aryl radicals, nucleophilic and also electrophilic alkyl radicals can cyclise to arenes providing products of an intramolecular homolytic aromatic substitution. Discussion on the mechanism is provided. Moreover, it will be shown that this chemistry has successfully been used in complex natural product synthesis. A subchapter is devoted to radical aryl migration reactions. Finally, reactions of aryl radicals with olefins are discussed. It is also shown that aryl radicals react efficiently with various heteroatom based radical acceptors for aryl-X bond formation (X = Se, S, Te, B, P).
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
John Wiley & Sons Ltd
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
RADICAL ARYLATION
dc.subject
HOMOLYTIC SUBSTITUTION
dc.subject
BIARYLS
dc.subject
ARYL RADICALS
dc.subject.classification
Química Orgánica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Radical Arylations
dc.type
info:eu-repo/semantics/publishedVersion
dc.type
info:eu-repo/semantics/bookPart
dc.type
info:ar-repo/semantics/parte de libro
dc.date.updated
2020-09-03T19:58:29Z
dc.journal.volume
2
dc.journal.pagination
1059-1094
dc.journal.pais
Reino Unido
dc.journal.ciudad
Chichester
dc.description.fil
Fil: Vaillard, Santiago Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Studer, Armido. Westfälische Wilhelms Universität; Alemania
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.wiley.com/WileyCDA/WileyTitle/productCd-0470971258.html
dc.conicet.paginas
2324
dc.source.titulo
Encylopedia of Radicals in Chemistry, Biology & Materials
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