Artículo

Novel thiol-derivatized zinc(II) phthalocyanines

Garcia Vior, María CeciliaIcon ; Cobice, Diego; Dicelio, Lelia Elina; Awruch, JosefinaIcon
Fecha de publicación: 05/2009
Editorial: Pergamon-Elsevier Science Ltd
Revista: Tetrahedron Letters
ISSN: 0040-4039
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Preparation and characterization of tetrasubstituted zinc(II) phthalocyanines in which sulfur is not linked to the macrocycle are reported herein for the first time. Thioacetic acid S-[3-(3,4-dicyano-phenoxy)-propyl]ester (4) was synthesized in 55% yield from 4-nitrophthalonitrile and thioacetic acid S-(3-hydroxy-propyl)ester (3). Tetrasusbtituted thiol-derivatized zinc(II) phthalocyanine 5 was obtained from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol. Treatment of 5 with sodium methoxide afforded phthalocyanine 6.
Palabras clave: THIOL-PHTHALOCYANINE , SYNTHESIS , SPECTTROSCOPY
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/114177
URL: https://www.sciencedirect.com/science/article/abs/pii/S0040403909004900
DOI: https://doi.org/10.1016/j.tetlet.2009.02.201
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Articulos(OCA HOUSSAY)
Articulos de OFICINA DE COORDINACION ADMINISTRATIVA HOUSSAY
Citación
Garcia Vior, María Cecilia; Cobice, Diego; Dicelio, Lelia Elina; Awruch, Josefina; Novel thiol-derivatized zinc(II) phthalocyanines; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 50; 21; 5-2009; 2467-2469
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