Mostrar el registro sencillo del ítem

dc.contributor.author
Montero, María de Los Angeles  
dc.contributor.author
Marozzi, Carlos Alberto  
dc.contributor.author
Gennero, Maria Rosa  
dc.contributor.author
Chialvo, Abel Cesar  
dc.date.available
2020-09-16T13:52:26Z  
dc.date.issued
2007-12  
dc.identifier.citation
Montero, María de Los Angeles; Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 52; 5; 12-2007; 2083-2090  
dc.identifier.issn
0013-4686  
dc.identifier.uri
http://hdl.handle.net/11336/114093  
dc.description.abstract
An alternative method for the determination of the kinetic parameters involved in the elementary steps of the reaction mechanism of the hydrogen electrode reaction is proposed. It is based on the determination of the variation of the polarization resistance in a tubular platinum electrode with a laminar flow of electrolyte as a function of the activity of protons of the electrolyte solution. A theoretical expression that relates the experimental variables and the equilibrium polarization resistance is developed, which takes into account the current distribution along the electrode surface. The results are compared with others obtained previously, contributing to the verification of the kinetic mechanism through a completely different experimental procedure.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Pergamon-Elsevier Science Ltd  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
HYDROGEN ELECTRODE REACTION  
dc.subject
KINETIC PARAMETERS  
dc.subject
PLATINUM  
dc.subject
POLARIZATION RESISTANCE  
dc.subject
TUBULAR ELECTRODE  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2020-09-03T19:24:07Z  
dc.journal.volume
52  
dc.journal.number
5  
dc.journal.pagination
2083-2090  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Montero, María de Los Angeles. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.description.fil
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral; Argentina  
dc.description.fil
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina  
dc.description.fil
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina  
dc.journal.title
Electrochimica Acta  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.electacta.2006.08.017