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dc.contributor.author
Li, Xiaoyu
dc.contributor.author
Lin, Jian
dc.contributor.author
Li, Lin
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Huang, Yike
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Pan, Xiaoli
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Collins, Sebastián Enrique
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Ren, Yujing
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Su, Yang
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Kang, Leilei
dc.contributor.author
Liu, Xiaoyan
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Zhou, Yanliang
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Wang, Hua
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Wang, Aiqin
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Qiao, Botao
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Wang, Xiaodong
dc.contributor.author
Zhang, Tao
dc.date.available
2020-09-14T14:48:37Z
dc.date.issued
2020-07
dc.identifier.citation
Li, Xiaoyu; Lin, Jian; Li, Lin; Huang, Yike; Pan, Xiaoli; et al.; Controlling CO2 Hydrogenation Selectivity by Metal-Supported Electron Transfer; Wiley VCH Verlag; Angewandte Chemie; 132; 18; 7-2020; 1-8
dc.identifier.issn
1433-7851
dc.identifier.uri
http://hdl.handle.net/11336/113905
dc.description.abstract
Tuning CO2 hydrogenation selectivity to obtain targeted value-added chemicals and fuels has attracted great yet everincreasing attention. How ever, a fundamental understanding of the nature to control the selectivity is still lacking, posing a challenge in catalyst design and development. Here, w e report our new discovery in ambient pressure CO2 hydrogenation reaction where selectivity canbe completely reversed by simply changing the crystal phases of TiO2 support (anatase- or rutile-TiO2) or changing metal loadings on anatase-TiO2. Operando spectroscopy and NAP-XPS studies reveal the determining factor is dif ferent electron transfer from metal to support under reaction conditions most probably as a result of the different extents of hydrogen spillover, which changes the adsorption and activation of the intermediate of CO. Based on this new finding, we can not only regulate CO2 hydrogenation selectivity but also tune catalytic performance in other important reactions, thus opening up a door for efficient catalyst development by rational design.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
CO2
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CRYSTAL PHASE
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ELECTRON TRANSFER
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HYDROGEN SPILLOVER
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SELECTIVITY
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Controlling CO2 Hydrogenation Selectivity by Metal-Supported Electron Transfer
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2020-09-03T19:20:13Z
dc.journal.volume
132
dc.journal.number
18
dc.journal.pagination
1-8
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Li, Xiaoyu. University Of Chinese Academy Of Sciences; China. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Lin, Jian. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Li, Lin. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Huang, Yike. University Of Chinese Academy Of Sciences; China. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Pan, Xiaoli. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Collins, Sebastián Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Ren, Yujing. University Of Chinese Academy Of Sciences; China. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Su, Yang. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Kang, Leilei. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Liu, Xiaoyan. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Zhou, Yanliang. University Of Chinese Academy Of Sciences; China. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Wang, Hua. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Wang, Aiqin. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
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Fil: Qiao, Botao. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Wang, Xiaodong. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.description.fil
Fil: Zhang, Tao. Dalian Institute Of Chemical Physics Chinese Academy Of Sciences; China
dc.journal.title
Angewandte Chemie
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202003847
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/anie.202003847
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