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dc.contributor.author
Karimi, Fahim
dc.contributor.author
Castro Riglos, Maria Victoria
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Santoru, Antonio
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Hoell, Armin
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Raghuwanshi, Vikram S.
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Milanese, Chiara
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Bergemann, Nils
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Pistidda, Claudio
dc.contributor.author
Nolis, Pau
dc.contributor.author
Baro, Maria D.
dc.contributor.author
Gizer, Gökhan
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Le, Thi-Thu
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Pranzas, P. Klaus
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Dornheim, Martin
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Klassen, Thomas
dc.contributor.author
Schreyer, Andreas
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Puszkiel, Julián Atilio
dc.date.available
2020-08-28T14:36:53Z
dc.date.issued
2018-06
dc.identifier.citation
Karimi, Fahim; Castro Riglos, Maria Victoria; Santoru, Antonio; Hoell, Armin; Raghuwanshi, Vikram S.; et al.; In Situ Formation of TiB2 Nanoparticles for Enhanced Dehydrogenation/Hydrogenation Reaction Kinetics of LiBH4-MgH2 as a Reversible Solid-State Hydrogen Storage Composite System; American Chemical Society; Journal of Physical Chemistry C; 122; 22; 6-2018; 11671-11679
dc.identifier.issn
1932-7447
dc.identifier.uri
http://hdl.handle.net/11336/112623
dc.description.abstract
To enhance the dehydrogenation/rehydrogenation kinetic behavior of the LiBH4-MgH2 composite system, TiF4 is used as an additive. The effect of this additive on the hydride composite system has been studied by means of laboratory and advanced synchrotron techniques. Investigations on the synthesis and mechanism upon hydrogen interaction show that the addition of TiF4 to the LiBH4-MgH2 composite system during the milling procedure leads to the in situ formation of well-distributed nanosized TiB2 particles. These TiB2 nanoparticles act as nucleation agents for the formation of MgB2 upon dehydrogenation process of the hydride composite system. The effect of TiB2 nanoparticles is maintained upon cycling.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
HIDROGEN STORAGE
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BORIDES
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NANOPARTICLES
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Ingeniería de los Materiales
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Ingeniería de los Materiales
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
In Situ Formation of TiB2 Nanoparticles for Enhanced Dehydrogenation/Hydrogenation Reaction Kinetics of LiBH4-MgH2 as a Reversible Solid-State Hydrogen Storage Composite System
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-10-15T17:55:38Z
dc.journal.volume
122
dc.journal.number
22
dc.journal.pagination
11671-11679
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Karimi, Fahim. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung ; Alemania
dc.description.fil
Fil: Castro Riglos, Maria Victoria. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
dc.description.fil
Fil: Santoru, Antonio. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung ; Alemania
dc.description.fil
Fil: Hoell, Armin. Helmholtz-Zentrum Berlin für Materialien und Energie; Alemania
dc.description.fil
Fil: Raghuwanshi, Vikram S.. Helmholtz-Zentrum Berlin für Materialien und Energie; Alemania
dc.description.fil
Fil: Milanese, Chiara. Universita Degli Studi Di Pavia; Italia
dc.description.fil
Fil: Bergemann, Nils. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Pistidda, Claudio. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Nolis, Pau. Universitat Autònoma de Barcelona; España
dc.description.fil
Fil: Baro, Maria D.. Universitat Autònoma de Barcelona; España
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Fil: Gizer, Gökhan. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Le, Thi-Thu. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Pranzas, P. Klaus. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Dornheim, Martin. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Klassen, Thomas. Helmholtz-zentrum Geesthacht - Zentrum Für Material- Und Küstenforschung; Alemania
dc.description.fil
Fil: Schreyer, Andreas. No especifíca;
dc.description.fil
Fil: Puszkiel, Julián Atilio. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
dc.journal.title
Journal of Physical Chemistry C
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.jpcc.8b02258
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.jpcc.8b02258
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