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dc.contributor.author
Riva, Julieta Soledad  
dc.contributor.author
Bassetto, V. C.  
dc.contributor.author
Girault, Hubert  
dc.contributor.author
Olaya, A. J.  
dc.date.available
2020-08-25T14:56:56Z  
dc.date.issued
2019-02  
dc.identifier.citation
Riva, Julieta Soledad; Bassetto, V. C.; Girault, Hubert; Olaya, A. J.; Standard ion transfer potential at the water|butyronitrile interface; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 835; 2-2019; 192-196  
dc.identifier.issn
1572-6657  
dc.identifier.uri
http://hdl.handle.net/11336/112326  
dc.description.abstract
Butyronitrile is an organic solvent stable enough to be used in photochemical reactions at liquid/liquid interfaces. However, it provides a rather short polarisation window making the analysis of ion transfer across the water|butyronitrile interface challenging. Here, steady-state cyclic voltammetry, at microhole-supported micro-interfaces, was used to measure Gibbs energies of transfer. A linear relationship between the standard Gibbs energies of ion partition for the water|butyronitrile interface and the water|1,2-dichloroethane and water|nitrobencene interfaces was found, making easy to extrapolate the Gibbs energy of other ions from this empiric correlation.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science Sa  
dc.rights
info:eu-repo/semantics/embargoedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
BUTYRONITRILE  
dc.subject
LIQUID/LIQUID INTERFACES  
dc.subject
MICROHOLE  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Standard ion transfer potential at the water|butyronitrile interface  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2020-08-20T20:29:15Z  
dc.journal.volume
835  
dc.journal.pagination
192-196  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Riva, Julieta Soledad. Swiss Federal Institute Of Technology Epfl; Suiza. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina  
dc.description.fil
Fil: Bassetto, V. C.. Swiss Federal Institute Of Technology Epfl; Suiza  
dc.description.fil
Fil: Girault, Hubert. Swiss Federal Institute Of Technology Epfl; Suiza  
dc.description.fil
Fil: Olaya, A. J.. Swiss Federal Institute Of Technology Epfl, Lausanne;  
dc.journal.title
Journal of Electroanalytical Chemistry  
dc.rights.embargoDate
2021-02-28  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jelechem.2019.01.041  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S1572665719300499