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dc.contributor.author
Canosa, Guadalupe
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dc.contributor.author
Alfieri, Paula V.
dc.contributor.author
Giudice, Carlos Alberto
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dc.date.available
2017-01-11T21:34:04Z
dc.date.issued
2014-09
dc.identifier.citation
Canosa, Guadalupe; Alfieri, Paula V.; Giudice, Carlos Alberto; High-solids, one-coat paints based on aliphatic epoxy resin-siloxanes for steel protection; Elsevier; Progress In Organic Coatings; 77; 9; 9-2014; 1459-1464
dc.identifier.issn
0300-9440
dc.identifier.uri
http://hdl.handle.net/11336/11171
dc.description.abstract
This research involved the design of high-solids, one-coat paints for the protection of metal structures with low maintenance requirements. The main paint components were: (i) an aliphatic epoxy resin cured with an aminosilane and chemically modified with alkoxysilanes as film-forming material, and (ii) rutile titanium dioxide as opaque pigment, a polysilicate strontium and zinc as corrosion inhibitor and, a synthetic calcium silicate and barites as extenders. Some paints displayed excellent performance in salt spray apparatus (degree of rusting) and in 100% relative humidity cabinet(degree of blistering). Results indicate that as the aliphatic epoxy resin/alkoxide ratio increased, the degree of rusting improved while the degree of blistering worsened, in total agreement with film permeability. In addition, binders based on dimethyldiethoxysilane, methyltriethoxysilane and tetraethoxysilane, in that order, displayed an improved corrosion performance and a decreased blistering resistance. The reactivity of alkoxides and the chemical interaction with the metal substrate supports the obtained results. Initial gloss and gloss and color retention improved as the alkoxide level increased; no significative differences were registered when the alkoxide type variable was considered. In summary, the use of alkoxides as modifiers of an aliphatic epoxy resin allowed the formulation of hybrid paints with high anticorrosive and weathering resistance performance. The more suitable hybrid organic–inoganic paint must be selected according to the requirements of each structure in service.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Aliphatic Epoxy
dc.subject
Siloxane
dc.subject
Permeability
dc.subject
Corrosion
dc.subject
Blistering
dc.subject
Optical Properties
dc.subject.classification
Recubrimientos y Películas
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dc.subject.classification
Ingeniería de los Materiales
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
High-solids, one-coat paints based on aliphatic epoxy resin-siloxanes for steel protection
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-01-11T19:18:50Z
dc.journal.volume
77
dc.journal.number
9
dc.journal.pagination
1459-1464
dc.journal.pais
Países Bajos
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dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Canosa, Guadalupe. Universidad Tecnologica Nacional. Facultad Reg.la Plata. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
dc.description.fil
Fil: Alfieri, Paula V.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina
dc.description.fil
Fil: Giudice, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Tecnología de Pinturas (i); Argentina. Universidad Tecnologica Nacional. Facultad Reg.la Plata. Departamento de Ingenieria Quimica; Argentina
dc.journal.title
Progress In Organic Coatings
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.porgcoat.2014.05.002
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S030094401400160X
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