Theoretical and FTIR Investigations of the Acetonitrile Hydrogenation Pathways on Platinum

Vogt, Lautaro; Schulte, Erica Daniela; Collins, Sebastián Enrique; Quaino, Paola Monica

doi:10.1007/s11244-019-01194-x

Artículo

Theoretical and FTIR Investigations of the Acetonitrile Hydrogenation Pathways on Platinum

Vogt, Lautaro; Schulte, Erica Daniela Icon

; Collins, Sebastián Enrique Icon

; Quaino, Paola Monica Icon

Fecha de publicación: 09/2019

Editorial: Springer/Plenum Publishers

Revista: Topics In Catalysis

ISSN: 1022-5528

Idioma: Inglés

Tipo de recurso: Artículo publicado

Clasificación temática:

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Resumen

The hydrogenation reaction of acetonitrile adsorbed on a platinum surface to produce amines has been investigated by theoretical and in situ infrared studies. An energetic, kinetics and vibrational analysis have been performed to unravel the elementary steps of the reaction and to clarify the mechanism. The comparison with the experiments allows us to identify an imine as a crucial intermediate for this reaction.

Palabras clave: DFT , IN SITU FTIR , NITRILE HYDROGENANTION , PLATINUM

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Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)

Identificadores

URI: http://hdl.handle.net/11336/110137

URL: https://link.springer.com/article/10.1007/s11244-019-01194-x

DOI: http://dx.doi.org/10.1007/s11244-019-01194-x

Colecciones

Articulos(IQAL)
Articulos de INSTITUTO DE QUIMICA APLICADA DEL LITORAL

Citación

Vogt, Lautaro; Schulte, Erica Daniela; Collins, Sebastián Enrique; Quaino, Paola Monica; Theoretical and FTIR Investigations of the Acetonitrile Hydrogenation Pathways on Platinum; Springer/Plenum Publishers; Topics In Catalysis; 62; 9-2019; 1076–1085

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