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dc.contributor.author
Mandal, Debdeep
dc.contributor.author
Stein, Felix
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Chandra, Shubhadeep
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Neuman, Nicolás Ignacio
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Sarkar, Pallavi
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Das, Shubhajit
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Kundu, Abhinanda
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Sarkar, Arighna
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Rawat, Hemant
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Pati, Swapan
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Chandrasekhar, Vadapalli
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Sarkar, Biprajit
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Jana, Anukul
dc.date.available
2020-07-02T14:38:08Z
dc.date.issued
2020-06
dc.identifier.citation
Mandal, Debdeep; Stein, Felix; Chandra, Shubhadeep; Neuman, Nicolás Ignacio; Sarkar, Pallavi; et al.; Trisubstituted Geminal Diazaalkenes Derived Transient 1,2-Carbodications; Royal Society of Chemistry; Chemical Communications; 6-2020; 1-5
dc.identifier.issn
1359-7345
dc.identifier.uri
http://hdl.handle.net/11336/108641
dc.description.abstract
Coulombic repulsion between two adjacent cation centres of 1,2-carbodications are known to decrease with π- and/or n-donor substituents by the positive charge delocalization. Here we report the delocalization of positive charge of transient 1,2-carbodications having one H-substituent by an intramolecular base-coordination. N-heterocyclic olefin (NHO) derived 2-pyrrolidinyl appended trisubstituted geminal diazaalkenes were employed for the generation of transient 1,2-carbodications through a 2-e chemical oxidation process. We have also studied the 1-e oxidation reaction of trisubstituted geminal diazaalkenes (electrochemically and chemically) and also studied them by in situ EPR spectroscopy.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
DICATION
dc.subject
N-HETEROCYCLIC OLEFIN
dc.subject.classification
Química Orgánica
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dc.subject.classification
Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
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dc.title
Trisubstituted Geminal Diazaalkenes Derived Transient 1,2-Carbodications
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2020-07-01T19:53:26Z
dc.journal.pagination
1-5
dc.journal.pais
Reino Unido
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dc.journal.ciudad
Cambridge
dc.description.fil
Fil: Mandal, Debdeep. Indian Institute of Technology; India
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Fil: Stein, Felix. Freie Universität Berlin; Alemania
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Fil: Chandra, Shubhadeep. Universitat Stuttgart;
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Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
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Fil: Sarkar, Pallavi. Indian Institute of Technology; India
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Fil: Das, Shubhajit. Indian Institute of Technology; India
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Fil: Kundu, Abhinanda. Indian Institute of Technology; India
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Fil: Sarkar, Arighna. Indian Institute of Technology; India
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Fil: Rawat, Hemant. Indian Institute of Technology; India
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Fil: Pati, Swapan. Indian Institute of Technology; India
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Fil: Chandrasekhar, Vadapalli. Indian Institute of Technology; India
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Fil: Sarkar, Biprajit. Universität Stuttgart;
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Fil: Jana, Anukul. Indian Institute of Technology; India
dc.journal.title
Chemical Communications
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2020/CC/D0CC02807J
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/D0CC02807J
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