Artículo

Ionic liquids and microwave irradiation as synergistic combination for polar Diels–Alder reactions using properly substituted heterocycles as dienophiles: A DFT study related

Mancini, Pedro Maximo Emilio; Ormachea, CarlaIcon ; Della Rosa, Claudia Daniela; Kneeteman, Maria NelidaIcon ; Suarez, Alejandra GracielaIcon ; Domingo, Luis R.
Fecha de publicación: 11/2012
Editorial: Pergamon-Elsevier Science Ltd
Revista: Tetrahedron Letters
ISSN: 0040-4039
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

For the DA reactions between nitropyrrole derivatives and isoprene, the combination of microwave irradiation and protic ionic liquid, has a notable synergistic effect. DFT calculations suggest that a supplementary energy ranking in the IR region of 1700-1400 cm-1 can favour the structural changes in the reactants to reach the TS.
Palabras clave: DIELS-ALDER , LIQUIDOS IONICOS
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/108005
URL: https://www.sciencedirect.com/science/article/pii/S0040403912016474
DOI: http://dx.doi.org/10.1016/j.tetlet.2012.09.071
Colecciones
Articulos(CCT - SANTA FE)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - SANTA FE
Articulos(IQUIR)
Articulos de INST.DE QUIMICA ROSARIO
Citación
Mancini, Pedro Maximo Emilio; Ormachea, Carla; Della Rosa, Claudia Daniela; Kneeteman, Maria Nelida; Suarez, Alejandra Graciela; et al.; Ionic liquids and microwave irradiation as synergistic combination for polar Diels–Alder reactions using properly substituted heterocycles as dienophiles: A DFT study related; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 53; 48; 11-2012; 6508-6511
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