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dc.contributor.author
Meiorin, Cintia
dc.contributor.author
Aranguren, Mirta Ines
dc.contributor.author
Mosiewicki, Mirna Alejandra
dc.date.available
2016-12-28T15:15:42Z
dc.date.issued
2015-01-19
dc.identifier.citation
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Polymeric networks based on tung oil: reaction and modification with green oil monomers; Elsevier; European Polymer Journal; 67; 19-1-2015; 551-560
dc.identifier.issn
0014-3057
dc.identifier.uri
http://hdl.handle.net/11336/10425
dc.description.abstract
A highly unsaturated vegetable oil (tung oil) was cationically copolymerized with a vegetable oil derived monomer, that replaces the more frequently used styrene. The synthesized comonomer was methyl ester of tung oil, obtained by transesterification of the plant oil with methanol. Alternatively, the incorporation of a green modifier, a commercial acrylated epoxidized soybean oil, was also considered. The use of any of these modifiers allowed preparing materials with an elevated content of bio-derived components.All the materials obtained presented good mechanical damping capacity, as well as dynamic mechanical properties comparable to analogous materials obtained by copolymerization with styrene. Incorporation of low concentrations of divinylbenzene in the formulations allowed increasing rigidity and glass transition temperatures (Tg) of the materials. One of the formulations prepared by copolymerization with the tung oil methyl ester presented shape memory behavior.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Tung Oil
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Methyl Ester
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Acrylated Epoxidized Soybean Oil
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Damping Properties
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Cationic Copolymerization
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Ingeniería de los Materiales
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Ingeniería de los Materiales
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INGENIERÍAS Y TECNOLOGÍAS
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Físico-Química, Ciencia de los Polímeros, Electroquímica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Polymeric networks based on tung oil: reaction and modification with green oil monomers
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2016-10-07T20:16:36Z
dc.journal.volume
67
dc.journal.pagination
551-560
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
dc.description.fil
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
dc.description.fil
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
dc.journal.title
European Polymer Journal
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305715000178
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.eurpolymj.2015.01.005
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