Artículo
Thermal effects on the electric deflection of toluene molecules
Fecha de publicación:
12/2008
Editorial:
Elsevier Science
Revista:
Chemical Physics Letters
ISSN:
0009-2614
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
A series of precise electric deflection experiments were done on a supersonic beam of toluene molecules in several expansion conditions and field strengths. We analyzed the effect of a gradual rotational cooling on the evolution of the beam profile by use of the available theories of asymmetric-top dipoles in electric fields. We have recorded from non-broadened (warm) to very broad and asymmetric (cold) profiles, and discussed this effect in terms of the Stark perturbation on the rotational motion.
Palabras clave:
Molecular beams
,
Electric deflection
,
Asymmetric top
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Articulos(CIOP)
Articulos de CENTRO DE INVEST.OPTICAS (I)
Articulos de CENTRO DE INVEST.OPTICAS (I)
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Carrera, Alvaro Daniel; Mobbili, Marcos Daniel; Moriena, Gustavo; Marceca, Ernesto José; Thermal effects on the electric deflection of toluene molecules; Elsevier Science; Chemical Physics Letters; 467; 1-3; 12-2008; 14-17
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