Artículo
Dispersed phase morphology of impact PP copolymers. Effects of blend composition as determined by TREF
Fecha de publicación:
08/04/2004
Editorial:
John Wiley & Sons Inc
Revista:
Polymer Engineering and Science
ISSN:
0032-3888
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Polypropylene (PP) blends, commercially known as 'impact polypropylene copolymers' (IPC), are produced by a sequential gas phase polymerization process. The final product is a complex mixture of polypropylene (PP) and a range of ethylene-propylene copolymers (EPC) with different ethylene contents. In the present work, the composition of three different IPC was estimated by performing a step elution mode Analytical Temperature Rising Elution Fractionation (TREF) separation. The recovered fractions were analyzed by Differential Scanning Calorimetry (DSC), Size Exclusion Chromatography (SEC) and Fourier Transform Infrared Spectroscopy (FTIR). The morphology was examined by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). Amorphous EPC were isolated in an independent way in order to perform a more careful characterization. The distinct particle size and shape of the dispersed phase for different IPC was interpreted in terms of the molecular characteristics of the blend components and their compositions.
Palabras clave:
Morphology
,
PPCopolymer
,
Composition
,
TREF
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(PLAPIQUI)
Articulos de PLANTA PILOTO DE INGENIERIA QUIMICA (I)
Articulos de PLANTA PILOTO DE INGENIERIA QUIMICA (I)
Citación
Zacur Martinez, Ruth Maria; Goizueta, Graciela Susana; Capiati, Numa Jose; Dispersed phase morphology of impact PP copolymers. Effects of blend composition as determined by TREF; John Wiley & Sons Inc; Polymer Engineering and Science; 40; 8; 8-4-2004; 1921-1930
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