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dc.contributor.author
Reinoso, Deborath Mariana
dc.contributor.author
Diaz, U.
dc.contributor.author
Frechero, Marisa Alejandra
dc.date.available
2020-03-25T12:56:28Z
dc.date.issued
2019-12
dc.identifier.citation
Reinoso, Deborath Mariana; Diaz, U.; Frechero, Marisa Alejandra; Structural study of functional hierarchical porous carbon synthesized from metal-organic framework template; Elsevier Ltd; Materials Today Chemistry; 14; 12-2019; 100188
dc.identifier.issn
2468-5194
dc.identifier.uri
http://hdl.handle.net/11336/100636
dc.description.abstract
In this work, nitrogen-doped hierarchical porous carbon (NPC) was obtained from an effective and facile synthesis route based on metal-organic framework (MOF)-drive approach using Zr-metal-organic framework (UiO-66-NH2) as a template. The structural analysis of synthesized NPC using different heat treatment was performed through X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and N2 adsorption-desorption isotherm at 77K characterization. The results achieved indicate that Zr-MOF is an appropriate starting precursor to attain functional carbon materials with remarkable physicochemical properties for potential advanced applications. Thereby, it was evidenced that the NPC synthesis temperature has an influence on resulting structural properties as well as nitrogen functionalities and amount. Thereby, the obtained NPC exhibits a disorder porous structure with high BET surface area (765–867 m2/g), pore size from microporous to mesoporous, and 3–4% of N content. Related to nitrogen functionalities, the heteroatom corresponds to quaternary, pyrrolic, and pyridinic bonding, indicating that it was successfully incorporated into the carbon framework.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Ltd
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
HIGHLY POROUS CARBON
dc.subject
N-DOPED CARBON
dc.subject
PHYSICOCHEMICAL CHARACTERIZATION
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TEMPLATE BASE SYNTHESIS
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ZIRCONIUM 1,4-DICARBOXYBENZENE MOF
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Structural study of functional hierarchical porous carbon synthesized from metal-organic framework template
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2020-02-26T20:10:19Z
dc.journal.volume
14
dc.journal.pagination
100188
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdan
dc.description.fil
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
dc.description.fil
Fil: Diaz, U.. Universidad Politécnica de Valencia; España
dc.description.fil
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.journal.title
Materials Today Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S2468519419302009
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.mtchem.2019.08.007
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