Artículo
Solving the Long-Standing Controversy of Long-Chain Alkanethiols Surface Structure on Au(111)
Torrelles, Xavier; Pensa, Evangelina Laura
; Cortés, Emiliano
; Salvarezza, Roberto Carlos
; Carro, Pilar; Hernández Guerrero, Cecilia; Ocal, Carmen; Barrena, Esther; Ferrer, Salvador
Fecha de publicación:
02/2018
Editorial:
American Chemical Society
Revista:
Journal of Physical Chemistry C
ISSN:
1932-7447
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The determination of the amount of gold adatoms and vacancies present at the thiol-gold interface of the (√3 × √3)-R30° lattice on Au(111), usually observed for long-chain alkanethiols, is crucial to complete our knowledge on the species resulting from the thiol-substrate interaction. While this issue has been addressed for short and intermediate alkanethiols where Au adatom-complexes of the type RS-Auad-SR, known as staples, are formed, this issue is still under discussion for long-chain alkanethiols where different and contradictory models have been proposed. In this report we present X-ray diffraction data of the (√3 × √3)-R30° structure for hexadecanethiol, allowing us to establish such basic structural features as the existence of Au adatoms and vacancies, the thiol adsorption-induced reconstruction of the surface, and the structure of the interface. These results allow us to reject the notion that vacancies and adatoms coexist within the same unit cell, and allow us to note that over the whole thiol-Au(111) interface the two exist in equal proportions. Vacancies appear on the gold surface as vacancy islands, and gold-adatoms appear flanked by two sulfur atoms, as observed on thiol-protected gold clusters and short thiols on Au(111). The coexistence of radicals and staples in the same (√3 × √3)-R30° cell is consistent with experiment and theory.
Palabras clave:
Alkanethiols
,
X-ray diffraction
,
thiol-adatom complex
,
surface chemistry
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Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Torrelles, Xavier; Pensa, Evangelina Laura; Cortés, Emiliano; Salvarezza, Roberto Carlos; Carro, Pilar; et al.; Solving the Long-Standing Controversy of Long-Chain Alkanethiols Surface Structure on Au(111); American Chemical Society; Journal of Physical Chemistry C; 122; 7; 2-2018; 3893-3902
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