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dc.contributor.author
Rengifo Herrera, Julian Andres  
dc.contributor.author
Blanco, Mirta Noemi  
dc.contributor.author
Pizzio, Luis Rene  
dc.date.available
2016-12-22T21:44:41Z  
dc.date.issued
2011-09-01  
dc.identifier.citation
Rengifo Herrera, Julian Andres ; Blanco, Mirta Noemi; Pizzio, Luis Rene; Photocatalytic bleaching of aqueous malachite green solutions by UV-A and blue-light-illuminated TiO2 spherical nanoparticles modified with tungstophosphoric acid; Elsevier Science; Applied Catalysis B: Environmental; 110; 2; 1-9-2011; 126-132  
dc.identifier.issn
0926-3373  
dc.identifier.uri
http://hdl.handle.net/11336/10007  
dc.description.abstract
Visible-light-responsive spherical TiO2 particles were prepared by the sol–gel method by adding urea as pore-forming agent and tungstophosphoric acid (TPA) in different ratios (20% and 30% w/w) and by annealing at 500 ◦C for 2 h. Visible light absorption is probably due to WOx formation (i.e. WO3) resulting from the partial degradation of TPA and evidenced by XPS spectra. Besides, 31P NMR and XPS results showed evidence about the existence of mostly unaltered TPA within TiO2 nanoparticles and on their surface, together with lacunar or dimeric species. TPA addition not only affected the optical properties of materials but also produced a strong decrease of their point of zero charge (pHpzc). Results obtained under UV-A irradiation revealed that aqueous malachite green (MG) solutions were efficiently bleached through the oxidative process of N-demethylation being the TiO2 powder containing 30% (w/w) of TPA (TiO2–TPA–30%) (100% of bleaching in 60 min) the most active even than Degussa P-25 (80% of MG bleaching in 60 min). On the other hand, when blue-light irradiation was used, TiO2–TPA–30% powder also revealed the highest photocatalytic bleaching of MG solutions which, as in the case of UVA light irradiation experiments, was oxidized through N-demethylation processes. Finally, experiments carried out using blue-light irradiation under N2 atmosphere showed that aqueous MG solutions were not bleached by TiO2 powders containing TPA  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Heterogeneous Tio2 Photocatalysis;  
dc.subject
Visible Light Responsive Tio2  
dc.subject
Tungstophosphoric Acid  
dc.subject
Malachite Green  
dc.subject.classification
Otras Ingeniería Química  
dc.subject.classification
Ingeniería Química  
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS  
dc.title
Photocatalytic bleaching of aqueous malachite green solutions by UV-A and blue-light-illuminated TiO2 spherical nanoparticles modified with tungstophosphoric acid  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2016-10-11T13:51:14Z  
dc.journal.volume
110  
dc.journal.number
2  
dc.journal.pagination
126-132  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Rengifo Herrera, Julian Andres . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina  
dc.description.fil
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina  
dc.description.fil
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina  
dc.journal.title
Applied Catalysis B: Environmental  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcatb.2011.08.034  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337311004103