On the symmetry of four particles in a one-dimensional box with harmonic interaction

Abstract

We show that a system of four particles in a one-dimensional box with a two-particle harmonic interaction can by described by means of the symmetry point group Oh. Group theory proves useful for the discussion of both the small-box and large-box regimes. We apply perturbation theory and obtain the corrections of first order for the lowest states. We carry out a simple Rayleigh–Ritz variational calculation with basis sets adapted to the symmetries of the system. We also obtain alternative variational results for the first three lowest energy levels that are more suitable for larger box sizes.