Artículo
Radical Fluoroalkylation Reactions
Fecha de publicación:
08/2018
Editorial:
American Chemical Society
Revista:
ACS Catalysis
ISSN:
2155-5435
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n ≥ 2), which effect both addition and substitution reactions on organic substrates, can be realized through a range of diverse methods such as the well-established visible-light transition-metal-mediated photocatalysis, organic-dye-photocatalyzed reactions, electron donor-acceptor complexes, and more recently frustrated Lewis pairs. Thus, perfluoroalkylation reactions of carbon-carbon multiple bonds, isocyanides, nitrones, hydrazones, β-keto esters, α-cyano arylacetates, sulfides, and (hetero)arenes will be described. Special emphasis will be placed on examples published after 2015, where higher fluorinated series of fluoroalkylating reagents are studied.
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Articulos(OCA HOUSSAY)
Articulos de OFICINA DE COORDINACION ADMINISTRATIVA HOUSSAY
Articulos de OFICINA DE COORDINACION ADMINISTRATIVA HOUSSAY
Citación
Barata Vallejo, Sebastian; Cooke, María Victoria; Postigo, A.; Radical Fluoroalkylation Reactions; American Chemical Society; ACS Catalysis; 8; 8; 8-2018; 7287-7307
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