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dc.contributor.author
Pedroso, Marcelo
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Gehn, Adriana Z.
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Stivanin, Mateus L.
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Larghi, Enrique Leandro
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Burrow, Robert A.
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Resende, Jackson A. L. C.
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Da Silva, Ubiratan F.
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Mostardeiro, Marco A.
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Dalcol, Ionara I.
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Morel, Ademir F.
dc.date.available
2020-01-06T17:10:01Z
dc.date.issued
2018-04
dc.identifier.citation
Pedroso, Marcelo; Gehn, Adriana Z.; Stivanin, Mateus L.; Larghi, Enrique Leandro; Burrow, Robert A.; et al.; Absolute configuration of clemateol; Sociedade Brasileira de Química; Journal of the Brazilian Chemical Society; 29; 4; 4-2018; 881-887
dc.identifier.issn
0103-5053
dc.identifier.uri
http://hdl.handle.net/11336/93629
dc.description.abstract
The present study reports the determination of absolute stereochemistry of clemateol, an irregular monoterpene containing an epoxy group, which was isolated as the main component from the essential oil of Calea clematidea (Asteraceae). Its absolute stereochemistry was unambiguously established on the basis of detailed nuclear magnetic resonance (NMR) spectroscopic evidence (3JH-H analysis, derivatization as Mosher's esters and nuclear Overhauser effect (NOESY) spectrum) and also by resonance scattering effects in the single crystal X-ray diffraction (XRD) resolution of its (R)-mandelic acid ester derivative.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Sociedade Brasileira de Química
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
CLEMATEOL
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CALEA CLEMATIDEA
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ESSENTIAL OIL
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ABSOLUTE STEREOCHEMISTRY
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Química Orgánica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Absolute configuration of clemateol
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-10-16T19:29:49Z
dc.identifier.eissn
1678-4790
dc.journal.volume
29
dc.journal.number
4
dc.journal.pagination
881-887
dc.journal.pais
Brasil
dc.description.fil
Fil: Pedroso, Marcelo. Universidade Federal de Santa Maria; Brasil
dc.description.fil
Fil: Gehn, Adriana Z.. Universidade Federal de Santa Maria; Brasil
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Fil: Stivanin, Mateus L.. Universidade Federal de Santa Maria; Brasil
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Fil: Larghi, Enrique Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
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Fil: Burrow, Robert A.. Universidade Federal de Santa Maria; Brasil
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Fil: Resende, Jackson A. L. C.. Universidade Federal Fluminense; Brasil
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Fil: Da Silva, Ubiratan F.. Universidade Federal de Santa Maria; Brasil
dc.description.fil
Fil: Mostardeiro, Marco A.. Universidade Federal de Santa Maria; Brasil
dc.description.fil
Fil: Dalcol, Ionara I.. Universidade Federal de Santa Maria; Brasil
dc.description.fil
Fil: Morel, Ademir F.. Universidade Federal de Santa Maria; Brasil
dc.journal.title
Journal of the Brazilian Chemical Society
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.21577/0103-5053.20170189
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info:eu-repo/semantics/altIdentifier/url/http://jbcs.sbq.org.br/default.asp?ed=265
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info:eu-repo/semantics/altIdentifier/url/https://s3-sa-east-1.amazonaws.com/publisher.gn1.com.br/jbcs.sbq.org.br/pdf/2017-0273SR.pdf
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