Artículo
In-situ XANES and XPD studies of NiO/Ce0.9Zr0.1O2 IT-SOFCs anode nanomaterial as catalyst in the CPOM reaction
Fecha de publicación:
25/07/2017
Editorial:
Elsevier Science
Revista:
Applied Catalysis A: General
ISSN:
0926-860X
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Resumen
The aim of this paper is to study the oxidation states of metal cations and the changes in the crystalline phases in NiO/Ce0.9Zr0.1O2 nanocatalysts under typical conditions of methane catalytic partial oxidation reaction by in-situ X ray absorption near edge spectroscopy (XANES) and X-ray powder diffraction (XPD) studies. The Ce0.9Zr0.1O2 mixed oxide was obtained by glycine-nitrate-combustion method, being the nickel incorporated by incipient wetness impregnation. The evolution of the crystalline structure with temperature and operating conditions was followed by in-situ XPD experiments and the oxidation states of Ce and Ni cations by in-situ XANES experiments at the Ce-LIII and Ni-K absorption edges. It was observed that NiO is completely reduced to Ni° at temperatures above 650 °C while Ce0.9Zr0.1O2 fluorite-like phase showed changes in lattice parameter due to cerium reduction and crystallite growth, but no phase transformations or segregations were observed. It was confirmed that Ni° is the active centre to activate methane molecule while Ce4+/Ce3+ ratio is strongly related with CO/CO2 concentration in the exhaust gas flow.
Palabras clave:
In Situ Xanes
,
In Situ Xpd
,
Mass Spectrometry
,
Methane Catalytic Oxidation
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(IFISUR)
Articulos de INSTITUTO DE FISICA DEL SUR
Articulos de INSTITUTO DE FISICA DEL SUR
Citación
Zimicz, Maria Genoveva; Prado, Fernando Daniel; Lamas, Diego Germán; Larrondo, Susana Adelina; In-situ XANES and XPD studies of NiO/Ce0.9Zr0.1O2 IT-SOFCs anode nanomaterial as catalyst in the CPOM reaction; Elsevier Science; Applied Catalysis A: General; 542; 25-7-2017; 296-305
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