Artículo
Molecular transport properties of ZIF-8 thin films in aqueous environments: The critical role of intergrain mesoporosity as diffusional pathway
Fecha de publicación:
01/2016
Editorial:
Elsevier Science
Revista:
Microporous and Mesoporous Materials
ISSN:
1387-1811
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
We report here the first use of electrochemical tools to quantify molecular transport from aqueous solutions into ZIF-8 MOF thin films. Our experimental findings reveal that molecular transport through ZIF-8 films in aqueous environments is purely dominated by solvent-filled intergrain mesoporosity and exhibits two well-defined transport regimes.
Palabras clave:
Metal-Organic Frameworks
,
Molecular Transport
,
Thin Films
,
Zif-8
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Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Tuninetti, Jimena Soledad; Rafti, Matias; Andrieu Brunsen, Annette; Azzaroni, Omar; Molecular transport properties of ZIF-8 thin films in aqueous environments: The critical role of intergrain mesoporosity as diffusional pathway; Elsevier Science; Microporous and Mesoporous Materials; 220; 1-2016; 253-257
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