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dc.contributor.author
Carvalho, Luciene S.
dc.contributor.author
Reyes, Patricio
dc.contributor.author
Pecchi Sanchez, Gina Angela
dc.contributor.author
Figoli, Nora Susana
dc.contributor.author
Pieck, Carlos Luis
dc.contributor.author
Rangel, Maria do Carmo
dc.date.available
2018-04-05T19:50:23Z
dc.date.issued
2001-11
dc.identifier.citation
Carvalho, Luciene S.; Reyes, Patricio; Pecchi Sanchez, Gina Angela; Figoli, Nora Susana; Pieck, Carlos Luis; et al.; Effect Of The Solvent Used During Preparation On The Properties Of Pt/Al 2 O 3 And Pt−Sn/Al 2 O 3 Catalysts; American Chemical Society; Industrial & Engineering Chemical Research; 40; 23; 11-2001; 5557-5563
dc.identifier.issn
0888-5885
dc.identifier.uri
http://hdl.handle.net/11336/40982
dc.description.abstract
The influence of the solvent (water, acetone, and ethanol) used during alumina impregnation on the properties of Pt/Al2O3 and Pt−Sn/Al2O3 catalysts was studied. Catalysts were characterized by H2 chemisorption, TEM, temperature-programmed reduction, ammonia temperature-programmed desorption, UV−vis spectroscopy and cyclohexane dehydrogenation, n-pentane isomerization, and n-octane reforming reactions. It was found that the catalysts prepared in ethanol has the highest metallic dispersion. The results are explained considering the Pt−Sn complex stability in the different solvents used during the preparation. Pt/Al2O3 (acetone) is the most active catalyst for isomerization while the activity of Pt−Sn/Al2O3 catalysts decreases in the order ethanol > acetone > water. The selectivity to aromatic hydrocarbons is related to isomerization activity, but there also exits a competition between hydrocracking and dehydrocyclization.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject.classification
Ingeniería Medioambiental y Geológica, Geotécnicas
dc.subject.classification
Ingeniería del Medio Ambiente
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
Effect Of The Solvent Used During Preparation On The Properties Of Pt/Al 2 O 3 And Pt−Sn/Al 2 O 3 Catalysts
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-03-16T15:41:17Z
dc.journal.volume
40
dc.journal.number
23
dc.journal.pagination
5557-5563
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Carvalho, Luciene S.. Universidade Federal da Bahia; Brasil
dc.description.fil
Fil: Reyes, Patricio. Universidad de Concepción; Chile
dc.description.fil
Fil: Pecchi Sanchez, Gina Angela. Universidad de Concepción; Chile
dc.description.fil
Fil: Figoli, Nora Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Rangel, Maria do Carmo. Universidade Federal da Bahia; Brasil
dc.journal.title
Industrial & Engineering Chemical Research
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ie000939t
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie000939t
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