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dc.contributor.author
Cabilla, Griselda
dc.contributor.author
Bonivardi, Adrian Lionel
dc.contributor.author
Baltanas, Miguel Angel
dc.date.available
2017-11-06T17:58:41Z
dc.date.issued
2001-05
dc.identifier.citation
Cabilla, Griselda; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; FTIR Study of the Adsorption of Methanol on Clean and Ca-promoted Pd/SiO2 Catalysts.; Academic Press Inc Elsevier Science; Journal of Catalysis; 201; 5-2001; 213-220
dc.identifier.issn
0021-9517
dc.identifier.uri
http://hdl.handle.net/11336/27666
dc.description.abstract
The adsorption and decomposition of methanol on a highly dispersed supported Pd/SiO2 catalyst (2% Pd w/w) prepared via ion exchange of [Pd(NH3)4]2+ in alkaline solution, together with two Ca-promoted preparations (Ca/Pd=2 at/at), where calcium was added either to the prereduced Pd crystallites or to the diammine palladium complex, were studied by FTIR at 298–623 K. Methanol adsorbs and reacts at 298 K on Pd/SiO2. The presence of Pd on the silica surface influences slightly the processes occurring on the support, where CH3OH is mostly adsorbed molecularly at room temperature, but readily forms very stable Si–O–CH3 groups upon heating. The dissociation of methanol via both O–H and C–O bond breaking is observed on Pd. The latter scission is only detected at 653 K. At room temperature, adsorbed CH3OH decomposes easily on the Pd crystallites, to give CO multicoordinated to the metal surface. Formyl species were also found at this temperature, but they promptly disappeared, above 393 K, when the catalyst was heated. Calcium promotion, either to the prereduced Pd or to its diammine complex precursor during the preparation steps, enhances methanol decomposition onto the catalyst surface, even at room temperature. With heating, formyl groups are replaced by mono- and bi-dentate formate species, which are chemisorbed on the support and/or the promoter. Bidentate formate is not as stable as the monodentate form and its IR band vanishes above 500 K. The observed features indicate that an excellent Ca–Pd intimacy was achieved with both types of promotion strategies.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Academic Press Inc Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Palladium
dc.subject
Methanol
dc.subject
Calcium Promotion
dc.subject.classification
Otras Ingeniería Química
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Ingeniería Química
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
FTIR Study of the Adsorption of Methanol on Clean and Ca-promoted Pd/SiO2 Catalysts.
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-11-03T20:27:44Z
dc.journal.volume
201
dc.journal.pagination
213-220
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Cabilla, Griselda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.journal.title
Journal of Catalysis
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1006/jcat.2001.3253
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