Artículo
FTIR kinetic study of the reactions of γ-caprolactone and γ-heptalactone initiated by Cl and OH radicals at 298 K and atmospheric pressure
Fecha de publicación:
02/2021
Editorial:
Elsevier Science
Revista:
Chemical Physics Letters
ISSN:
0009-2614
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Rate coefficients were determined for the reactions of the furanones (C6H10O2) (C7H12O2) with OH radicals (k1 and k2) and with Cl atoms (k3 and k4) at 298 K, to be (in cm3 molecule−1 s−1): k1 = (6.4 ± 1.4) × 10−12, k2 = (8.8 ± 1.9) × 10−12, k3 = (1.30 ± 0.41) × 10−10, k4 = (1.70 ± 0.34) × 10−10, respectively. kOH correlates with kCl and SAR show C5 as the favored site of H abstraction.
Palabras clave:
Lactones
,
FTIR
,
Kinetics
,
Reactivity
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Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Baptista Ruiz, Andrea Carolina; Gibilisco, Rodrigo Gastón; Wiesen, Peter; Teruel, Mariano Andres; FTIR kinetic study of the reactions of γ-caprolactone and γ-heptalactone initiated by Cl and OH radicals at 298 K and atmospheric pressure; Elsevier Science; Chemical Physics Letters; 765; 138313; 2-2021; 1-7
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