Artículo

A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones

Cortés, IvánIcon ; Kaufman, Teodoro SaulIcon ; Bracca, Andrea Beatriz JuanaIcon
Fecha de publicación: 05/2018
Editorial: The Royal Society
Revista: Royal Society Open Science
ISSN: 2054-5703
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The use of CeCl3·7H2O as an efficient and eco-friendly promoter for the convenient synthesis of methoximes derived from aromatic aldehydes and ketones, is reported. The transformations entail the use of equimolar amounts of MeONH2·HCl and NaOAc in EtOH at 50°C, and no special precautions are needed with regard to the presence of oxygen. The scope and limitations of the transformation were studied and a reaction mechanism was proposed.
Palabras clave: CERIUM (III) CHLORIDE , PROMOTED REACTION , METHOXIMATION , ECO-FRIENDLY TRANSFORMATION
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/87164
URL: https://royalsocietypublishing.org/doi/10.1098/rsos.180279
DOI: http://dx.doi.org/10.1098/rsos.180279
Colecciones
Articulos(IQUIR)
Articulos de INST.DE QUIMICA ROSARIO
Citación
Cortés, Iván; Kaufman, Teodoro Saul; Bracca, Andrea Beatriz Juana; A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones; The Royal Society; Royal Society Open Science; 5; 5; 5-2018; 1-14
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