Artículo
Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
Pinto, Leandro M. C.; Spohr, Eckhard; Quaino, Paola Monica
; Santos, Elizabeth del Carmen
; Schmickler, Wolfgang
Fecha de publicación:
06/2013
Editorial:
Wiley
Revista:
Angewandte Chemie International Edition
ISSN:
1521-3773
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction.
Palabras clave:
Silver
,
Deposition
,
Electron Transfer
Archivos asociados
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Identificadores
Colecciones
Articulos(CCT - SANTA FE)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - SANTA FE
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - SANTA FE
Articulos(IFEG)
Articulos de INST.DE FISICA ENRIQUE GAVIOLA
Articulos de INST.DE FISICA ENRIQUE GAVIOLA
Citación
Pinto, Leandro M. C.; Spohr, Eckhard; Quaino, Paola Monica; Santos, Elizabeth del Carmen; Schmickler, Wolfgang; Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition; Wiley; Angewandte Chemie International Edition; 52; 30; 6-2013; 7883–7885
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