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dc.contributor.author Cagnola, Edgardo Alberto
dc.contributor.author Quiroga, Monica Esther
dc.contributor.author Liprandi, Domingo Antonio
dc.contributor.author L'argentiere, Pablo Cesar
dc.date.available 2019-04-11T15:02:39Z
dc.date.issued 2004-10
dc.identifier.citation Cagnola, Edgardo Alberto; Quiroga, Monica Esther; Liprandi, Domingo Antonio; L'argentiere, Pablo Cesar; Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene; Elsevier Science; Applied Catalysis A: General; 274; 1-2; 10-2004; 205-212
dc.identifier.issn 0926-860X
dc.identifier.uri http://hdl.handle.net/11336/74033
dc.description.abstract Complexes of Rh, Ru, Pd and Ni with tridecylamine and chloride as ligands were prepared and tested as heterogeneous catalysts for the hydrogenation of cyclohexene. The Wilkinson's complex was used as a reference catalyst. Supported complexes turned out to be more active and more resistant to a sulphur poison than the homogeneous systems also evaluated for comparison. The rhodium-tridecylamine complex was the most active, slightly less than the Wilkinson's complex but more sulphur resistant than the latter. XPS and FTIR studies revealed that the complexes kept their chemical identity and remained attached to the support even after the reaction. This suggests that the coordination compounds studied are the catalytically active species or that they are converted to the actual active species during the catalytic process.
dc.format application/pdf
dc.language.iso eng
dc.publisher Elsevier Science
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject CATALYTIC HYDROGENATION
dc.subject HETEROGENEOUS CATALYSTS
dc.subject TRANSITION METAL COMPLEXES
dc.subject.classification Otras Ingeniería del Medio Ambiente
dc.subject.classification Ingeniería del Medio Ambiente
dc.subject.classification INGENIERÍAS Y TECNOLOGÍAS
dc.title Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2019-04-01T16:11:07Z
dc.journal.volume 274
dc.journal.number 1-2
dc.journal.pagination 205-212
dc.journal.pais Países Bajos
dc.journal.ciudad Amsterdam
dc.description.fil Fil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina
dc.description.fil Fil: Quiroga, Monica Esther. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
dc.description.fil Fil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina
dc.description.fil Fil: L'argentiere, Pablo Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title Applied Catalysis A: General
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2004.07.001
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04006271
dc.conicet.fuente individual


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    Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"

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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)