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dc.contributor.author
Cagnola, Edgardo Alberto
dc.contributor.author
Quiroga, Monica Esther
dc.contributor.author
Liprandi, Domingo Antonio
dc.contributor.author
L'argentiere, Pablo Cesar
dc.date.available
2019-04-11T15:02:39Z
dc.date.issued
2004-10
dc.identifier.citation
Cagnola, Edgardo Alberto; Quiroga, Monica Esther; Liprandi, Domingo Antonio; L'argentiere, Pablo Cesar; Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene; Elsevier Science; Applied Catalysis A: General; 274; 1-2; 10-2004; 205-212
dc.identifier.issn
0926-860X
dc.identifier.uri
http://hdl.handle.net/11336/74033
dc.description.abstract
Complexes of Rh, Ru, Pd and Ni with tridecylamine and chloride as ligands were prepared and tested as heterogeneous catalysts for the hydrogenation of cyclohexene. The Wilkinson's complex was used as a reference catalyst. Supported complexes turned out to be more active and more resistant to a sulphur poison than the homogeneous systems also evaluated for comparison. The rhodium-tridecylamine complex was the most active, slightly less than the Wilkinson's complex but more sulphur resistant than the latter. XPS and FTIR studies revealed that the complexes kept their chemical identity and remained attached to the support even after the reaction. This suggests that the coordination compounds studied are the catalytically active species or that they are converted to the actual active species during the catalytic process.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Catalytic Hydrogenation
dc.subject
Heterogeneous Catalysts
dc.subject
Transition Metal Complexes
dc.subject.classification
Otras Ingeniería del Medio Ambiente
dc.subject.classification
Ingeniería del Medio Ambiente
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-04-01T16:11:07Z
dc.journal.volume
274
dc.journal.number
1-2
dc.journal.pagination
205-212
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina
dc.description.fil
Fil: Quiroga, Monica Esther. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
dc.description.fil
Fil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina
dc.description.fil
Fil: L'argentiere, Pablo Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title
Applied Catalysis A: General
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2004.07.001
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04006271


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    Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"

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