Artículo
Oxidative dehydrogenation of propane and n-butane over alumina supported vanadium catalysts
Fecha de publicación:
12/2004
Editorial:
Planta Piloto de Ingeniería Química
Revista:
Latin American Applied Research
ISSN:
0327-0793
e-ISSN:
1851-8796
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Structural properties of vanadium dispersed species on γ-A1203 are investigated with the scope to detect changes related with V loading in the oxidative dehydrogenation (ODH) of propane and nbutane. XPS, FTIR, and FTIR of absorbed pyridine were used to study the nature of vanadium supported species. Tetrahedral V5+ and probably V4+ species were detected. For vanadium loadings higher than 4.3 % wt octahedral species were also observed. In the n-butane ODH reaction, the selectivity to ODH products decreases when vanadium content increases. However, for propane ODH, the selectivity seems to be independent of vanadium loadings. Low oxygen/alkane feeding ratios favor selectivity to olefins. It is also shown that low V loading catalysts reach selectivities as good as best reported V-Mg-O catalyst.
Palabras clave:
Oxidative Dehydrogenation
,
Vanadium Catalysts
,
Propane
,
N-Butane
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Identificadores
Colecciones
Articulos(INIQUI)
Articulos de INST.DE INVEST.PARA LA INDUSTRIA QUIMICA (I)
Articulos de INST.DE INVEST.PARA LA INDUSTRIA QUIMICA (I)
Citación
Murgia, Viviana; Sham, Edgardo Ling; Gottifredi, Juan Carlos Agustin; Farfan Torres, Elsa Monica; Oxidative dehydrogenation of propane and n-butane over alumina supported vanadium catalysts; Planta Piloto de Ingeniería Química; Latin American Applied Research; 34; 12-2004; 75-82
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