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dc.contributor.author
Ben Altabef, Aída  
dc.contributor.author
H. Oberhammer  
dc.date.available
2018-10-10T20:07:29Z  
dc.date.issued
2002-11  
dc.identifier.citation
Ben Altabef, Aída; H. Oberhammer; Gas phase structure of diiodosilane SiH2I2; Elsevier Science; Journal of Molecular Structure; 641; 2-3; 11-2002; 259-261  
dc.identifier.issn
0022-2860  
dc.identifier.uri
http://hdl.handle.net/11336/62130  
dc.description.abstract
The molecular structure of diiodosilane has been determined by gas electron diffraction. Assuming C2v symmetry, only the S-I bond length (2.423(3) Å) and the I-Si-I bond angle (110.8(4)°) could be determined accurately in this experiment. The experimental geometric parameters and vibrational frequencies which were reported earlier are compared to calculated values derived with the HF approximation and DFT methods (B3LYP and SVWN) using 3-21G* basis sets and effective core potentials.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Diiodosilane  
dc.subject
Gas Electron Diffraction  
dc.subject
Infrared Spectra  
dc.subject
Quantum Chemical Calculations  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Gas phase structure of diiodosilane SiH2I2  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-10-09T20:31:23Z  
dc.journal.volume
641  
dc.journal.number
2-3  
dc.journal.pagination
259-261  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Ben Altabef, Aída. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina  
dc.description.fil
Fil: H. Oberhammer. Universität Tübingen; Alemania  
dc.journal.title
Journal of Molecular Structure  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/S0022-2860(02)00354-X  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S002228600200354X  

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