Artículo
Selective charge transfer in donor/acceptor systems bridged by Tröger base derivatives
Ramirez, Cristina Lujan
; Procaccini, Raul Ariel
; Chesta, Carlos Alberto
; Parise, Alejandro Ruben
; Vera, Domingo Mariano Adolfo
Fecha de publicación:
10/2013
Editorial:
Elsevier Science
Revista:
Organic Electronics
ISSN:
1566-1199
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Recently, unusual charge transfer properties of two triarylamines bridged through an aliphatic bridge (Tröger base) have been reported. The donor/acceptor couple was shown to have an important electronic coupling between its centers for the hole transfer, although in the absence of a π linker. In contrast, we here show, by combining first principles calculations with experimental studies, that the bridge has a practically null role in coupling the electron transfer. This sharp contrast might present an interesting potential in the design of molecular devices.
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Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos(CCT - MAR DEL PLATA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - MAR DEL PLATA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - MAR DEL PLATA
Articulos(INTEMA)
Articulos de INST.DE INV.EN CIENCIA Y TECNOL.MATERIALES (I)
Articulos de INST.DE INV.EN CIENCIA Y TECNOL.MATERIALES (I)
Citación
Ramirez, Cristina Lujan; Procaccini, Raul Ariel; Chesta, Carlos Alberto; Parise, Alejandro Ruben; Vera, Domingo Mariano Adolfo; Selective charge transfer in donor/acceptor systems bridged by Tröger base derivatives; Elsevier Science; Organic Electronics; 14; 10; 10-2013; 2564-2572
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