Mostrar el registro sencillo del ítem
dc.contributor.author
Calandra, Julia
dc.contributor.author
Postigo, Jose Alberto
dc.contributor.author
Russo, Diana
dc.contributor.author
Sbarbati Nudelman, Norma
dc.contributor.author
Tereñas, Juan José
dc.date.available
2017-03-27T15:56:02Z
dc.date.issued
2010-10
dc.identifier.citation
Calandra, Julia; Postigo, Jose Alberto; Russo, Diana ; Sbarbati Nudelman, Norma; Tereñas, Juan José; Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation; Wiley; Journal Of Physical Organic Chemistry; 23; 10; 10-2010; 944-949
dc.identifier.issn
0894-3230
dc.identifier.uri
http://hdl.handle.net/11336/14270
dc.description.abstract
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-induced hydrosilylation reaction of C[BOND]C multiple bonds in water with tris(trimethylsilyl)silane ((Me3Si)3SiH). Photochemical radical initiation in the absence of a chemical radical precursor other than the silane is found to be a very efficient and convenient method to induce the hydrosilylation reaction of C[BOND]C multiple bonds of organic compounds with (Me3Si)3SiH in water. This new alternate radical-based methodology studied in water is confronted with the classical radical thermal initiation of hydrosilylation reactions triggered through the thermal decomposition of azo compounds.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Photochemical Initiation
dc.subject
Radical Reactions in Water
dc.subject
Silyl Radicals
dc.subject.classification
Química Orgánica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-03-21T20:12:30Z
dc.identifier.eissn
1099-1395
dc.journal.volume
23
dc.journal.number
10
dc.journal.pagination
944-949
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Hoboken
dc.description.fil
Fil: Calandra, Julia. Universidad de Belgrano; Argentina
dc.description.fil
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Belgrano; Argentina
dc.description.fil
Fil: Russo, Diana . Universidad de Belgrano; Argentina
dc.description.fil
Fil: Sbarbati Nudelman, Norma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
dc.description.fil
Fil: Tereñas, Juan José. Universidad de Belgrano; Argentina
dc.journal.title
Journal Of Physical Organic Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/poc.1732/abstract
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/poc.1732
Archivos asociados