A combined RCM-Bischler-Napieralski strategy towards the synthesis of the carbon skeleton of excentricine and related stephaoxocanes

Larghi, Enrique Leandro; Kaufman, Teodoro Saul

doi:10.1016/j.tet.2008.08.005

Artículo

A combined RCM-Bischler-Napieralski strategy towards the synthesis of the carbon skeleton of excentricine and related stephaoxocanes

Larghi, Enrique Leandro Icon

; Kaufman, Teodoro Saul Icon

Fecha de publicación: 10/2008

Editorial: Pergamon-Elsevier Science Ltd

Revista: Tetrahedron

ISSN: 0040-4020

Idioma: Inglés

Tipo de recurso: Artículo publicado

Clasificación temática:

Química Orgánica

Resumen

A convenient synthetic approach to a cyclodeca[ij]isoquinoline derivative, which embodies the carbon skeleton of excentricine and related stephaoxocanes, is described. The synthesis involves the combined use of ring closing metathesis and Bischler-Napieralski cyclizations for the construction of the homocyclic and nitrogen-bearing rings, respectively.

Palabras clave: BISCHLER-NAPIERALSKI , EXCENTRICINE ANALOGUE , MACROLACTAM CYCLIZATION , RCM , STEPHAOXOCANES

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Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)

Identificadores

URI: http://hdl.handle.net/11336/136553

URL: https://www.sciencedirect.com/science/article/abs/pii/S0040402008014531

DOI: http://dx.doi.org/10.1016/j.tet.2008.08.005

Colecciones

Articulos(IQUIR)
Articulos de INST.DE QUIMICA ROSARIO

Citación

Larghi, Enrique Leandro; Kaufman, Teodoro Saul; A combined RCM-Bischler-Napieralski strategy towards the synthesis of the carbon skeleton of excentricine and related stephaoxocanes; Pergamon-Elsevier Science Ltd; Tetrahedron; 64; 42; 10-2008; 9921-9927

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