Artículo
Night-time atmospheric degradation of a series of butyl methacrylates
Fecha de publicación:
11/2016
Editorial:
Elsevier Science
Revista:
Chemical Physics Letters
ISSN:
0009-2614
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Rate coefficients for the reactions of NO3 with n-butyl methacrylate (k1), iso-butyl methacrylate (k2) and tert-butyl methacrylate (k3) have been determined at 298 K and atmospheric pressure using the relative rate method. The following rate coefficients (×10−15 cm3 molecule−1 s−1) were obtained for the first time: k1 = (5.5 ± 2.6), k2 = (5.8 ± 2.8) and k3 = (5.6 ± 2.5). The NO3 reactions of these compounds could contribute to the removal of NOx and as NOy reservoirs. The potential importance for the tropospheric nitrogen budget of these reactions is discussed and atmospheric lifetimes for the butyl esters are calculated.
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Teruel, Mariano Andres; Pérez López, Rocío Soledad; Barnes, Ian; Blanco, Maria Belen; Night-time atmospheric degradation of a series of butyl methacrylates; Elsevier Science; Chemical Physics Letters; 664; 11-2016; 205-212
Compartir
Altmétricas