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dc.contributor.author
Marugan, Javier
dc.contributor.author
Van Grieken, Rafael
dc.contributor.author
Cassano, Alberto Enrique
dc.contributor.author
Alfano, Orlando Mario
dc.date.available
2017-10-05T20:21:53Z
dc.date.issued
2007-12
dc.identifier.citation
Marugan, Javier; Van Grieken, Rafael; Cassano, Alberto Enrique; Alfano, Orlando Mario; Comparison of Empirical and Kinetic Modeling of the Photocatalytic Oxidation of Cyanide; De Gruyter; International Journal of Chemical Reactor Engineering; 5; 1; 12-2007; 1-10
dc.identifier.issn
1542-6580
dc.identifier.uri
http://hdl.handle.net/11336/26040
dc.description.abstract
An intrinsic kinetic model based on the reaction mechanism of the photocatalytic oxidation of cyanide with TiO2 has been developed and applied to the results of experiments carried out using different catalyst concentrations, initial concentrations of cyanide and incident radiation fluxes. The results of the kinetic modeling have been compared with the use of an empirical model equation generated following the response surface methodology; a statistical procedure to correlate the influence of several factors on a response variable.
The kinetic model reproduces the experimental data with a relative error below 13%, slightly lower than that obtained with the empirical model equation. In contrast with the latter, the kinetic model is based on the intrinsic photocatalytic reaction mechanism and takes into account the radiation profiles inside the photoreactor. Consequently, after validating the model in a broad range of experimental conditions, it could be applied to any other reactor configuration, allowing the simulation and optimization of the radiation and reaction rate fields with scalingup and photoreactor design purposes.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
De Gruyter
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Kinetic Model
dc.subject
Cyanide Oxidation
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Emipirical Model
dc.subject
Comparison
dc.subject.classification
Otras Ingeniería Química
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Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Comparison of Empirical and Kinetic Modeling of the Photocatalytic Oxidation of Cyanide
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-10-04T14:45:01Z
dc.journal.volume
5
dc.journal.number
1
dc.journal.pagination
1-10
dc.journal.pais
Alemania
dc.journal.ciudad
Berlín
dc.description.fil
Fil: Marugan, Javier. Universidad Rey Juan Carlos; España
dc.description.fil
Fil: Van Grieken, Rafael. Universidad Rey Juan Carlos; España
dc.description.fil
Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.journal.title
International Journal of Chemical Reactor Engineering
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.2202/1542-6580.1529
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/ijcre.2007.5.1/ijcre.2007.5.1.1529/ijcre.2007.5.1.1529.xml
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