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dc.contributor.author Marugan, Javier
dc.contributor.author Van Grieken, Rafael
dc.contributor.author Cassano, Alberto Enrique
dc.contributor.author Alfano, Orlando Mario
dc.date.available 2017-10-05T20:21:53Z
dc.date.issued 2007-12
dc.identifier.citation Marugan, Javier; Van Grieken, Rafael; Cassano, Alberto Enrique; Alfano, Orlando Mario; Comparison of Empirical and Kinetic Modeling of the Photocatalytic Oxidation of Cyanide; De Gruyter; International Journal of Chemical Reactor Engineering; 5; 1; 12-2007; 1-10
dc.identifier.issn 1542-6580
dc.identifier.uri http://hdl.handle.net/11336/26040
dc.description.abstract An intrinsic kinetic model based on the reaction mechanism of the photocatalytic oxidation of cyanide with TiO2 has been developed and applied to the results of experiments carried out using different catalyst concentrations, initial concentrations of cyanide and incident radiation fluxes. The results of the kinetic modeling have been compared with the use of an empirical model equation generated following the response surface methodology; a statistical procedure to correlate the influence of several factors on a response variable. The kinetic model reproduces the experimental data with a relative error below 13%, slightly lower than that obtained with the empirical model equation. In contrast with the latter, the kinetic model is based on the intrinsic photocatalytic reaction mechanism and takes into account the radiation profiles inside the photoreactor. Consequently, after validating the model in a broad range of experimental conditions, it could be applied to any other reactor configuration, allowing the simulation and optimization of the radiation and reaction rate fields with scalingup and photoreactor design purposes.
dc.format application/pdf
dc.language.iso eng
dc.publisher De Gruyter
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject KINETIC MODEL
dc.subject CYANIDE OXIDATION
dc.subject EMIPIRICAL MODEL
dc.subject COMPARISON
dc.subject.classification Otras Ingeniería Química
dc.subject.classification Ingeniería Química
dc.subject.classification INGENIERÍAS Y TECNOLOGÍAS
dc.title Comparison of Empirical and Kinetic Modeling of the Photocatalytic Oxidation of Cyanide
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2017-10-04T14:45:01Z
dc.journal.volume 5
dc.journal.number 1
dc.journal.pagination 1-10
dc.journal.pais Alemania
dc.journal.ciudad Berlín
dc.description.fil Fil: Marugan, Javier. Universidad Rey Juan Carlos; España
dc.description.fil Fil: Van Grieken, Rafael. Universidad Rey Juan Carlos; España
dc.description.fil Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.journal.title International Journal of Chemical Reactor Engineering
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.2202/1542-6580.1529
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/ijcre.2007.5.1/ijcre.2007.5.1.1529/ijcre.2007.5.1.1529.xml


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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)